Tratamento de efluentes de indústria alimentícia com o uso de hidrocalumita como adsorvente
Palavras-chave:
adsorção, corantes alimentícios, hidrocalumita, efluentesResumo
A remoção do colorido das águas naturais é um dos grandes problemas ambientais, uma vez que estes corantes são de difícil degradação devido a sua estrutura complexa e origem sintética. No entanto, com o aumento do rigor da legislação ambiental e devido às pressões da comunidade, tal problema precisa ser sanado, com o uso de tecnologias que sejam eficientes e economicamente viáveis. Neste estudo foi utilizado o adsorvente hidrocalumita (HDL‑CaAl-NO3), sintetizada pelo método de coprecipitação em pH variável, para adsorção de corantes sintéticos alimentícios, amarelo crepúsculo e azul brilhante. O HDL foi caracterizado por difração de raios X, espectroscopia no infravermelho, microscopia eletrônica de varredura, análise termogravimétrica, área superficial e volume de poros. Os resultados mostraram que para o corante azul brilhante, uma dosagem de 2° g/L de hidrocalumita já é suficiente para remover mais de 90% de sua coloração, atingindo 99% de eficiência com apenas 5° g/L. Todavia, para o amarelo crepúsculo essa mesma dosagem só remove 45% do corante, sendo necessária uma dosagem de 10° g/L para atingir 98% de eficiência. Observou-se também que a cinética de adsorção para os dois corantes ocorre de forma diferente, tendo em vista que a adsorção é mais rápida para o azul brilhante em relação ao amarelo crepúsculo.
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